Clear all secret missions as Nero, Dante, or V.

Clear Mission 05 without V's demons getting stalemated. (Heaven or Hell excluded)

Acquire all of V's skills.

Use more than 500,000 Red Orbs total with Dr. Faust.

Clear Mission 07 with both Nero and V.

Reach Max Level with Deadshot

Unlock a Villain Synergy

Achieve 39 Stars in Riddler AR Challenges

Collect 10 Riddler Trophies

Defeat 1,000 enemies total.

Get Penguin to overhaul a piece of gear

Clear Missions 19 and 20 without continuing as Nero, Dante, or V. (Heaven or Hell excluded)

Complete the game on Human mode as Nero, Dante, or V.